Retreating back to Commander Clash's island, the Planeteers use an ionizer weapon to draw out the toxic chemicals from Captain Planet, allowing him to re-challenge Captain Pollution. Blight throws a Pollution Pod at Captain Planet, severely draining him of his power. The latter initially has the upper hand over the former when Dr. Blight, Captain Planet is summoned, and the Eco-Villains respond by summoning Captain Pollution. Later on, after the Planeteers get their rings back from Dr. Being badly defeated, Captain Pollution left the island and returned to the ship where the Eco-Villains had gathered together, returning to the Rings, just as Captain Planet normally does whenever he's weakened. Upon being summoned, Captain Pollution was sent to Commander Clash's island, where he fought the ex-military commando, and lost after Kwame and Gi discovered that pure things such as water and sunlight can hurt Captain Pollution. Blight's computer, the idea for the villains to combine their powers in the same manner as the Planeteers came into play. Initially when presented their rings, the five Eco-Villains saw them as mere tools to be used in attempting to defeat the Planeteers, but after a careful observation by MAL, Dr. Blight, after presenting the five Rings of Destruction to fellow Eco-Villains Duke Nukem, Sly Sludge, Verminous Skumm, and Looten Plunder.

In 'Mission to Save the Earth: Parts 1 & 2', Captain Pollution is first created by Dr. Also, there is a California Valley twang to his voice. His costume is the same color and style as Planet's, but the chest is torn in the middle with two halves of a cracked version of Planet's chest symbol on either side. His hair is red and styled in a Widow's peak, and his eyes are red as well. Captain Pollution resembles Captain Planet, but his skin is pale yellow, and covered in brown lesions.

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